5  Nutrient Indicators

The state thresholds used in the chlorophyll a, total nitrogen, and total phosphorus visualizations come from Florida State Surface Water Quality Standards within the Florida Administrative Code.

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5.1 Summary

Daily average dissolved oxygen values were mostly within or above their average ranges so far in 2024 (Figure 5.1); however, Pine Island and Pellicer Creek (Figure 5.1; Figure 5.1 (d)) had above average and below daily average range. In previous years, dissolved oxygen values at Pine Island (Figure 5.2 (a)) and Pellicer Creek (Figure 5.3 (a)) frequently fell below the 2 mg/L hypoxia threshold, but so far in 2024, there have not been any dissolved oxygen readings below that threshold (Figure 5.2 (b), (Figure 5.3 (b)).

Chlorophyll a values were often higher than average at all stations this year, especially at Pine Island, San Sebastian, and Pellicer Creek (Figure 5.4). Annual geometric mean (AGM) chlorophyll a values were high and above the state threshold levels at all stations, except for Fort Matanzas (Figure 5.4). Annual geometric mean (AGM) chlorophyll a values were high and above the state threshold levels at all stations, except for Fort Matanzas (Figure 5.5), (Figure 5.5 (c)). The AGM will likely change for all stations as more data are added throughout the year.

Ammonium (NH4) concentrations for 2024 were below monthly means most of year at all four stations (Figure 5.7). Concentrations were above average at the two southern sites, Fort Matanzas and Pellicer Creek in September (Figure 5.7 (c); Figure 5.7 (d)) but were below average at Pine Island and San Sebastian (Figure 5.7 (a); Figure 5.7 (b)).

Total Kjeldahl Nitrogen (TKN) concentrations were higher than average at all stations in January and March, but concentrations were lower most of Q2 and Q3 (Figure 5.9). Concentrations in September were above average for Fort Matanzas and Pellicer Creek (Figure 5.9 (c); Figure 5.9 (d))

Total phosphorus concentrations were below the state threshold at all stations in 2024 with the exception of February at Pine Island which was missing data (Figure 5.10). Fort Matanzas experienced higher than average TP values for January – March and July (Figure 5.10 (c)) and San Sebastian had lower than average TP values for February – September.

Relatively high levels of orthophosphate were observed at Pine Island and San Sebastian in January (Figure 5.10 (a), Figure 5.10 (b)) and below average levels were found in April – June for San Sebastian, Fort Matanzas, and Pellicer Creek (Figure 5.10 (b), (Figure 5.10 (c)).

5.2 Data

5.2.1 Dissolved Oxygen

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.1: Historical daily range of dissolved oxygen at each SWMP water quality station with current year daily average overlaid in blue. Horizontal dashed red line indicates 2mg/L hypoxia threshold.

Dissolved oxygen at Pine Island has been uncharacteristically low in the past two years.

(a) For the past five years

(b) For the current 2024 year

Figure 5.2: Continuous dissolved oxygen at Pine Island with monthly average overlaid in solid gray line. Conditions are indicated as good when above 5 mg/L, fair between 2 and 5 mg/L, and poor if less than 2 mg/L.

Pellicer Creek is located within a waterbody with known impairments for dissolved oxygen, chlorophyll a, and fecal coliform bacteria. As such, this station frequently experiences low dissolved oxygen values, particularly in the summer months (Figure 5.3).

(a) For the past five years

(b) For the current 2024 year

Figure 5.3: Continuous dissolved oxygen at Pellicer Creek with monthly average overlaid in solid gray line. Conditions are indicated as good when above 5 mg/L, fair between 2 and 5 mg/L, and poor if less than 2 mg/L.

5.2.2 Chlorophyll a

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.4: Historical monthly chlorophyll a at each SWMP water quality station with current year monthly value overlaid in red. Horizontal dashed blue line indicates the state threshold, as found in F.A.C 62-302.530.

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.5: Annual geometric means of monthly chlorophyll a at each SWMP water quality station. Horizontal dashed blue line indicates the state threshold, as found in F.A.C 62-302.530. Values exceeding the threshold are indicated in red. The 2024 value is based upon data to date and does not equal an entire year of data.

5.2.3 Nitrogen

5.2.3.1 Total Nitrogen

TN is calculated by adding TKN and NO23. It accounts for the inorganic nitrogen fraction as well as larger pools of organic bioavailable forms.

Several of the NO23 values fell below the Florida Department of Environmental Protection Central Lab’s minimum detection limit and therefore TN was not able to be calculated and is missing for quite a few months at all the stations (Figure 5.6). This was especially true at Fort Matanzas which has the least amount of TN data (Figure 5.6 (c)).

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.6: Historical monthly total nitrogen at each SWMP water quality station with current year monthly value overlaid in red. Horizontal dashed blue line indicates the state threshold, as found in F.A.C 62-302.530.

5.2.3.2 Ammonium

Ammonium is directly measured in our samples and is a key inorganic nutrient assimilated by phytoplankton in primary production.

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.7: Historical monthly ammonium at each SWMP water quality station with current year monthly value overlaid in red.

5.2.3.3 Nitrite + Nitrate

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.8: Historical monthly ammonium at each SWMP water quality station with current year monthly value overlaid in red.

5.2.3.4 Total Kjeldahl Nitrogen

TKN is the total concentration of organic nitrogen and ammonia. It is directly measured in our samples.

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.9: Historical monthly total kjeldahl nitrogen at each SWMP water quality station with current year monthly value overlaid in red.

5.2.4 Phosphorus

5.2.4.1 Total Phosphorus

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.10: Historical monthly total phosphorus at each SWMP water quality station with current year monthly value overlaid in red. Horizontal dashed blue line indicates the state threshold, as found in F.A.C 62-302.530.

5.2.4.2 Orthophosphate

(a) Pine Island

(b) San Sebastian

(c) Fort Matanzas

(d) Pellicer Creek

Figure 5.11: Historical monthly orthophosphate at each SWMP water quality station with current year monthly value overlaid in red.